
Journal of Organometallic Chemistry p. 303 - 310 (1989)
Update date:2022-08-02
Topics:
Kalinin, V. N.
Derunov, V. V.
Lusenkova, M. A.
Petrovsky, P. V.
Kolobova, N. E.
Isocyanides (RNC) insert into the M=C bond in Cp(OC)2Mn=C=CHPh (I), to give the intermediates Cp(OC)2Mn(RN=C=C=CHPh), R=t-Bu (II), C6H11 (III), CH2Ph (IV).The reaction of II-IV with H2O gives Cp(OC)2Mn-cis-Ph(H)C=C(H)C(O)NHR>, R=t-Bu (V), C6H11 (VI), CH
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