Reactions of vinylidene and allenylidene cymantrene derivatives with isonitriles

DOI: 10.1016/0022-328X(89)85170-8

Source and publish data:

Journal of Organometallic Chemistry p. 303 - 310 (1989)

Update date:2022-08-02

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Authors:

Kalinin, V. N.

Derunov, V. V.

Lusenkova, M. A.

Petrovsky, P. V.

Kolobova, N. E.

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Article abstract of DOI:10.1016/0022-328X(89)85170-8

Isocyanides (RNC) insert into the M=C bond in Cp(OC)2Mn=C=CHPh (I), to give the intermediates Cp(OC)2Mn(RN=C=C=CHPh), R=t-Bu (II), C6H11 (III), CH2Ph (IV).The reaction of II-IV with H2O gives Cp(OC)2Mn, R=t-Bu (V), C6H11 (VI), CH

Full text of DOI:10.1016/0022-328X(89)85170-8

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