Journal of the American Chemical Society p. 4829 - 4837 (1989)
Update date:2022-08-03
Topics: Stereoselective synthesis Total synthesis Organic synthesis Protecting group Reaction Conditions Chiral Auxiliary Chemistry Structural Elucidation
Danishefsky
Lee
The total synthesis of the antitumor title compound has been accomplished. Among the key steps was an iodolactonization of a cyclohexadiene bearing a neighboring carboxamido group mediated by an ortho-stannylated phenol. A series of cis vicinal functional
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