Carbon-Carbon Bond Formation at the γ-Position of Dienolates via the Germanium Masked Dienolates

DOI: 10.1039/c39880001639

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1639 - 1640 (1988)

Update date:2022-07-31

Topics:

Authors:

Yamamoto, Yoshinori

Hatsuya, Satoshi

Yamada, Jun-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39880001639

Trapping of the lithium dienolate (1), derived from 3-methyl-2-butenoate, with Me3GeX (X = Br or Cl gives the α-germylated derivative (2), which reacts with various electrophiles at the γ-position.

Full text of DOI:10.1039/c39880001639

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:ethyl 5-methoxy-3-methyl-5-phenyl-2-pentenoate

Cas No:120982-22-1

R&D Labs maybe for 120982-22-1

Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road
Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Dongguan Albiya Energy Science and Technology Co.,Ltd

Contact:+86-769-22181286

Address:Huanan Industial Park, Dongguan,China
Shaanxi Lighte Optoelectronics Material Co., Ltd.

Contact:+86-29-88320728-622/619/620

Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.

Relevant to this article

1H NMR Spectroscopy of Cycloadducts of 1,5- and 1,6-Diazaphenanthrene Phenacylides

Doi:10.1002/mrc.1260291018
(1991)
Development and application of a near-infrared fluorescence probe for oxidative stress based on differential reactivity of linked cyanine dyes

Doi:10.1021/ja910090v
(2010)
Cascade synthesis of 2-Amino-5-(4-methoxyphenyl)-4-phenyl-1,3-thiazole by Reaction of 4-Chloro-N-[2,2-dichloro-1-(4-methoxyphenyl)-2-phenylethyl] benzenesulfonamide with Thiourea

Doi:10.1134/S1070428011040178
(2011)
Doi:10.1039/jr9520002778
(1952)
NEW FUNCTIONALIZATIONS OF OXANORBORNENIC SYSTEMS VIA 1,3-DIPOLAR CYCLOADDITIONS WITH C,N-DIPHENYLNITRONE

Doi:10.1016/S0040-4020(01)86090-7
(1988)
SYNTHESIS OF INDOLES FROM PYRIDINIUM SALTS. 6. REACTION OF 3-NITROQUINOLINIUM SALTS WITH KETONES IN THE PRESENCE OF AMINES

Doi:10.1007/BF00475693
(1988)

Article Doi