Journal of the Chemical Society. Chemical communications p. 1548 - 1549 (1989)
Update date:2022-09-26
Topics:
Kresge, A. J.
Schepp, N. P.
The bromination of 2,4,6-trimethylacetophenone, whose unusual kinetics were once thought to be the result of slow, sterically hindered addition of bromine to the enol, was found to be a ring- rather than a side-chain-substitution reaction; kinetic and thermodynamic charactristics of this keto-enol system were determined by a combination of flash-photolytic and conventional kinetic techniques and were found to be little different from those of the parent (unsubstituted) acetophenone keto-enol system.
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