
Angewandte Chemie - International Edition p. 144 - 147 (2010)
Update date:2022-08-06
Topics:
Terao, Jun
Tomita, Masahiro
Singh, Surya Prakash
Kambe, Nobuaki
chemical equation presented Unwringing the ring: Methylenecyclopropanes reacted with vinyl and aryl Grignard reagents in the presence of a nickel catalyst to afford vinyl- and arylmagnesation products, respectively, through a selective C - C bond cleavage (see scheme). The reaction provides a new method for the preparation of substituted homoallyl and allyl Grignard reagents.
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