Metallacyclic metaloxycarbene complexes from 1,2-didehydrobenzene group 4 metallocenes and metal carbonyls

DOI: 10.1021/om00110a034

Source and publish data:

Organometallics p. 2037 - 2044 (1989)

Update date:2022-08-03

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Authors:

Erker, Gerhard

Dorf, Ulrich

Lecht, Rainer

Ashby, Michael T.

Aulbach, Michael

Schlund, Rüger

Krüger, Carl

Mynott, Richard

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Article abstract of DOI:10.1021/om00110a034

Thermally generated (η²-1,2-didehydrobenzene)titanocene and -zirconocene react with hexacarbonylmolybdenum or -tungsten at 90°C to give five-membered metallacyclic titan- and zirconoxycarbene complexes 4. The carbene complex Cp₂ZrOC[

Full text of DOI:10.1021/om00110a034

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