Journal of Organic Chemistry p. 3002 - 3004 (1989)
Update date:2022-07-29
Topics:
Gawley, Robert E.
Rein, Kathleen
Chemburkar, Sanjay
A comparison of 1,3- and 1,5-asymmetric induction shows the former to have far greater selectivity in the methylation of chiral dipole-stabilized organolithiums.The asymmetric alkylation of N-benzyloxazolidinones is employed as the key step in a new synthesis of primary amines by asymmetric alkylation α to nitrogen.
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