Chiral Synthesis of (+)-Methyl 5-epi-Shikimate by Asymmetric Diels-Alder Reaction of (S)S-3-(2-Pyridylsulfinyl)acrylate

DOI: 10.1055/s-1989-27191

Source and publish data:

Synthesis p. 189 - 191 (1989)

Update date:2022-08-03

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Authors:

Takahashi, Tamiko

Iyobe, Akira

Arai, Yoshitsugu

Koizumi, Toru

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Article abstract of DOI:10.1055/s-1989-27191

(+)-Methyl 5-epi-shikimate (9) was synthesized diastereoselectively by asymmetric Diels-Alder reaction of (S)_S-3-(2-pyridylsulfinyl)acrylate (1) with furan.

Full text of DOI:10.1055/s-1989-27191

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Product name:(1'R,2'S,5'R)-Menthyl (1R,2R,3S,4S)-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>hept-5-ene-2-carboxylate

Cas No:121388-49-6

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