
Tetrahedron Letters p. 5285 - 5286 (1988)
Update date:2022-07-30
Topics:
Ikegami, Satoru
Katsuki, Tsutomu
Yamaguchi, Masaru
The Ireland alcohol, a key intermediate for the synthesis of tirandamycin A, was prepared in a stereoselective manner, where titanium-mediated <2,3>Wittig rearrangement and iodolactonization were used as key steps for the construction of four consecutive asymmetric centers.
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