STRUCTURAL ELUCIDATION AND A NOVEL REDUCTIVE CLEAVAGE OF RIBOFURANOSYL RING C-1 - O BOND OF THE INTRAMOLECULAR C-ARYLATION PRODUCT OF TRI-O-BENZYL-β-D-RIBOFURANOSYL FLUORIDE

DOI: 10.1016/S0040-4039(01)80374-9

Source and publish data:

Tetrahedron Letters p. 1115 - 1118 (1989)

Update date:2022-08-05

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Authors:

Araki, Younosuke

Mokubo, Eiji

Kobayashi, Naoki

Nagasawa, Jun'ichi

Ishido, Yoshiharu

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Article abstract of DOI:10.1016/S0040-4039(01)80374-9

Treatment of 2,3,5-tri-o-benzyl-β-D-ribofuranosyl fluoride (1) with BF3*OEt2 in CH2Cl2 gave the intramolecular C-arylation product (2) formed from the reaction with the 2-O-benzyl group in a 83percent yield.Catalytic transfer hydrogenolysis of 2 using HCO

Full text of DOI:10.1016/S0040-4039(01)80374-9

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