(Polyhalophenyl)silver(I) complexes as arylating agents: Crystal structure of ClO4

DOI: 10.1016/0022-328X(88)80367-X

Source and publish data:

Journal of Organometallic Chemistry p. 129 - 138 (1988)

Update date:2022-08-02

Topics:

Authors:

Uson, Rafael

Laguna, Antonio

Fernandez, Eduardo J.

Mendia, Aranzazu

Jones, Peter G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(88)80367-X

The arylsilver derivatives AgR (R=C6F5, 2,4,6-C6F3H2 or C6Cl5) react with chlorogold(I) precursors , to give the corresponding arylgold complexes in good yield.With gold precursors in higher oxidation state, AgC6Cl5 either causes reduction to gold(I) or gives no reaction, whereas AgC6F5 and AgC6F3H2 lead to gold(II) complexes (R2Au(dppm)AuR2) or gold(III) complexes .

Full text of DOI:10.1016/0022-328X(88)80367-X

Products guided by the article

Product name:Silver, (2,4,6-trifluorophenyl)-

Cas No:121772-59-6

R&D Labs maybe for 121772-59-6

Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
Hangzhou innopharma technology Co,.Ltd.(expird)

Contact:+86-13388601988

Address:Room845,lixin building, moganshan road, hangzhou, china

Relevant to this article

Ir(III)-Catalyzed room-temperature synthesis of multisubstituted benzofurans initiated by C-H activation of -aryloxy ketones

Doi:10.1055/s-0030-1260981
(2011)
Cembrenediols in the curing of tobacco. X-ray crystal structures of β-cembrenediol and α-cembreneketol

Doi:10.1016/0031-9422(88)80427-8
(1988)
AN OPTICALLY ACTIVE ALLENE MACRODIOLIDE: A VERSATILE KEY INTERMEDIATE LEADING TO (-)-PYRENOPHORIN AND (+)-DIBENZOMACRODIOLIDES

Doi:10.1016/S0040-4039(00)82285-6
(1988)
Structure-activity relationship study on α₁ adrenergic receptor antagonists from beer

Doi:10.1016/j.bmcl.2009.08.068
(2009)
Two-component dendritic chain reactions: experiment and theory

Doi:10.1021/ja910839n
(2010)
PPh₃-catalyzed reactions of alkyl propiolates with N-tosylimines: A facile synthesis of alkyl 2-[aryl(tosylimino)methyl]acrylate and an insight into the reaction mechanism

Doi:10.1002/chem.200902105
(2010)

Article Doi