STUDIES DIRECTED TOWARDS TAXANES. PREPARATION OF α-KETOLS BY OXIDATIVE RING-OPENING OF EPOXIDES.

DOI: 10.1016/S0040-4039(00)86699-X

Source and publish data:

Tetrahedron Letters p. 2163 - 2166 (1988)

Update date:2022-07-30

Topics:

Authors:

Trost, Barry M.

Fray, Jonathan M.

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Article abstract of DOI:10.1016/S0040-4039(00)86699-X

Protonic acid promoted ring-opening of epoxide by dimethyl sulphoxides at room temperature followed by treatment with diisopropylethylamine at -78 deg C, affords α-ketols in modest to good yields.

Full text of DOI:10.1016/S0040-4039(00)86699-X

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