APPLICATION OF REDUCTIVE, SINGLE ELECTRON TRANSFER PROCESSES TO THE GENERATION AND CYCLIZATION OF ω-UNSATURATED α-AMINO RADICALS

DOI: 10.1016/S0040-4039(00)82428-4

Source and publish data:

Tetrahedron Letters p. 6685 - 6688 (1988)

Update date:2022-08-03

Topics:

Authors:

Martin, Stephen F.

Yang, Chih-Ping

Laswell, William L.

Rueeger, Heinrich

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Article abstract of DOI:10.1016/S0040-4039(00)82428-4

Subjection of ω-unsaturated iminium salts 1 to dissolving metal reduction with samarium diiodide in the presence of camphorsulfonic acid afforded the corresponding α-amino radicals 2, which underwent facile cyclization via a 5-exo mode of closure leading

Full text of DOI:10.1016/S0040-4039(00)82428-4

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