CONSECUTIVE DIELS-ALDER- MICHAEL ADDITION - 1.3-DIPOLAR CYCLOADDITION PROCESSES

DOI: 10.1016/S0040-4039(00)95268-7

Source and publish data:

Tetrahedron Letters p. 609 - 612 (1989)

Update date:2022-08-05

Topics:

Authors:

Donegan, Gregory

Grigg, Ronald

Heaney, Frances

Surendrakumar, Sivagnanasundram

Warnock, William J.

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Article abstract of DOI:10.1016/S0040-4039(00)95268-7

The first examples of a new consecutive Diels-Alder - Michael addition- 1,3-dipolar cycloaddition process are described.The 1,3-dipolar cycloaddition step involves a nitrone generated in situ from an oxime and an electronegative olefin.The overall process results in the creation of six new stereocenters.

Full text of DOI:10.1016/S0040-4039(00)95268-7

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