Synthesis, structure, and acylating properties of 1-aroyloxy-4,5-dimethyl- 1,2,3-triazoles

DOI: 10.1039/P19890000619

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 619 - 621 (1989)

Update date:2022-09-26

Topics:

Authors:

Theocharis

Maroulis

Hadjiantoniou-Maroulis

Alexandrou

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19890000619

Lead tetra-acetate oxidation of α-hydroxyimino aroylhydrazones of biacetyl (1) gives 1-aroyloxy-4,5-dimethyl-1,2,3-triazoles (2), the structures of which were confirmed by X-ray analysis. A mechanism for this reaction is discussed. The products (2) are effective aroylating agents for the amino function under mild conditions.

Full text of DOI:10.1039/P19890000619

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:HONC(CH₃)C(CH₃)NNHC(O)C₆H₄CH₃-p

Cas No:122081-17-8

R&D Labs maybe for 122081-17-8

Beijing eternalchem Co,. Ltd

Contact:+86-10-59484199

Address:No.58-A1026 Liangguan Street
Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road
Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.

Relevant to this article

Diastereoselective Intramolecular Aldol-Type Trapping of Zwitterionic Intermediates by Ketones for the Synthesis of Spiro[chroman-4,3′-oxindole] Derivatives

Doi:10.1002/adsc.201600998
(2017)
Achiral additives dramatically enhance enantioselectivities in the BINOL-Ti(IV) complex catalyzed aldol condensations of aldehydes with Chan's diene

Doi:10.1016/j.tetasy.2010.01.008
(2010)
SYNTHESIS OF DIPHENYLDICYANODIPHOSPHINE

Doi:10.1007/BF00953741
(1989)
Anti-HSV-1 activity and mechanism of action of some new synthesized substituted pyrimidine, thiopyrimidine and thiazolopyrimidine derivatives

Doi:10.1016/j.ejmech.2009.12.057
(2010)
Fine-tuning alkyne cycloadditions: Insights into photochemistry responsible for the double-strand DNA cleavage via structural perturbations in diaryl alkyne conjugates

Doi:10.3762/bjoc.7.93
(2011)
ADDITION DE COMPOSES INSATURES SUR LES PHOSPHORANES MONOCYCLIQUES A LIAISON P-H

Doi:10.1016/S0040-4020(01)89798-2
(1988)

Article Doi