Synthesis, structure, and acylating properties of 1-aroyloxy-4,5-dimethyl- 1,2,3-triazoles

DOI: 10.1039/P19890000619

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 619 - 621 (1989)

Update date:2022-09-26

Topics:

Authors:

Theocharis

Maroulis

Hadjiantoniou-Maroulis

Alexandrou

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19890000619

Lead tetra-acetate oxidation of α-hydroxyimino aroylhydrazones of biacetyl (1) gives 1-aroyloxy-4,5-dimethyl-1,2,3-triazoles (2), the structures of which were confirmed by X-ray analysis. A mechanism for this reaction is discussed. The products (2) are effective aroylating agents for the amino function under mild conditions.

Full text of DOI:10.1039/P19890000619

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:HONC(CH₃)C(CH₃)NNHC(O)C₆H₄CH₃-p

Cas No:122081-17-8

R&D Labs maybe for 122081-17-8

SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu
Yangzhou Zhongbao Pharmaceutical Co.,Ltd

Contact:+86-514-88290838

Address:Jiangsu Baoying county economic develpment zone in baoying avenue91
Taizhou Crene Biotechnology co.ltd

Contact:86-576-88813233 88205808

Address:Economic Developed Zone of Taizhou Zhejiang China
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai

Relevant to this article

Diastereoselective Intramolecular Aldol-Type Trapping of Zwitterionic Intermediates by Ketones for the Synthesis of Spiro[chroman-4,3′-oxindole] Derivatives

Doi:10.1002/adsc.201600998
(2017)
Achiral additives dramatically enhance enantioselectivities in the BINOL-Ti(IV) complex catalyzed aldol condensations of aldehydes with Chan's diene

Doi:10.1016/j.tetasy.2010.01.008
(2010)
SYNTHESIS OF DIPHENYLDICYANODIPHOSPHINE

Doi:10.1007/BF00953741
(1989)
Anti-HSV-1 activity and mechanism of action of some new synthesized substituted pyrimidine, thiopyrimidine and thiazolopyrimidine derivatives

Doi:10.1016/j.ejmech.2009.12.057
(2010)
Fine-tuning alkyne cycloadditions: Insights into photochemistry responsible for the double-strand DNA cleavage via structural perturbations in diaryl alkyne conjugates

Doi:10.3762/bjoc.7.93
(2011)
ADDITION DE COMPOSES INSATURES SUR LES PHOSPHORANES MONOCYCLIQUES A LIAISON P-H

Doi:10.1016/S0040-4020(01)89798-2
(1988)

Article Doi