Synthesis, structure, and acylating properties of 1-aroyloxy-4,5-dimethyl- 1,2,3-triazoles

DOI: 10.1039/P19890000619

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 619 - 621 (1989)

Update date:2022-09-26

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Authors:

Theocharis

Maroulis

Hadjiantoniou-Maroulis

Alexandrou

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Article abstract of DOI:10.1039/P19890000619

Lead tetra-acetate oxidation of α-hydroxyimino aroylhydrazones of biacetyl (1) gives 1-aroyloxy-4,5-dimethyl-1,2,3-triazoles (2), the structures of which were confirmed by X-ray analysis. A mechanism for this reaction is discussed. The products (2) are effective aroylating agents for the amino function under mild conditions.

Full text of DOI:10.1039/P19890000619

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