Journal of the Chemical Society. Perkin transactions I p. 619 - 621 (1989)
Update date:2022-09-26
Topics:
Theocharis
Maroulis
Hadjiantoniou-Maroulis
Alexandrou
Lead tetra-acetate oxidation of α-hydroxyimino aroylhydrazones of biacetyl (1) gives 1-aroyloxy-4,5-dimethyl-1,2,3-triazoles (2), the structures of which were confirmed by X-ray analysis. A mechanism for this reaction is discussed. The products (2) are effective aroylating agents for the amino function under mild conditions.
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