Chemistry - A European Journal p. 2040 - 2044 (2010)
Update date:2022-08-05
Topics:
Zhao, Xiaoxi
Otten, Edwin
Song, Datong
Stephan, Douglas W.
Boron bends over for nickel : The Ni complexes [{t Bu2PC≡ CB(QFs)2]Ni(cod)] (1) and [({tBu2PC≡ CB(C6F5)2}Ni(NCMc))] (2) derived from the reaction between the phosphinoalkynyl-borane tBu2PC≡CB(C 6F5)2 and [Ni(cod)2] exhibit an unprecedented metal-alkyne interaction in which the borane substituent bends towards the metal affording a Ni→B dative interaction. (Chemical Equation Representation). (Chemical Equation Representation).
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