Tin(II) Chloride Dihydrate - a Mild Reagent for the Transformation of 6-Nitro-Δ5-steroids to 5α-Hydroxy-6-ketosteroids

DOI: 10.1039/c39900000498

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 498 - 499 (1990)

Update date:2022-08-05

Topics:

Authors:

Singhal, Gireesh M.

Das, Nalin B.

Sharma, Ram P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900000498

Reaction of excess hydrated tin(II) chloride with 6-nitro-Δ⁵-steroids (1a-g) and (5) in tetrahydrofuran furnishes 5α-hydroxy-6-ketosteroids (2a-g) and (6) respectively, in good yields.

Full text of DOI:10.1039/c39900000498

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Z-mandelaldoxime

Cas No:129171-02-4

R&D Labs maybe for 129171-02-4

Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian
Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0
PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China

Relevant to this article

A novel preparation of thiazolo[5,4-c]pyridines and the synthesis of some imidazo[5,4-c]pyridines and oxazolo[4,5-c] pyridines

Doi:10.1002/jhet.5570270316
(1990)
Discovery of 1-[2-(2,4-Dimethylphenylsulfanyl)phenyl]piperazine (Lu AA21004): A Novel Multimodal Compound for the Treatment of Major Depressive Disorder

Doi:10.1021/jm101459g
(2011)
Selective catalytic hydrogenation of an olefin moiety in the presence of a terminal alkyne function

Doi:10.1016/0040-4039(90)80166-J
(1990)
ORTHO LITHIATION DIRECTED BY AMINO GROUPS ON SILICON IN PHENYLSILANE DERIVATIVES

Doi:10.1016/0040-4039(90)80186-P
(1990)
Two new antibiotics from the Red Sea sponge Psammaplysilla purpurea. Total ¹³C-NMR line assignment of psammaplysins A and B and aerothionin

Doi:10.1016/S0040-4020(01)91843-5
(1983)
Doi:10.1016/S0020-1693(00)80734-3
(1984)

Article Doi