Tin(II) Chloride Dihydrate - a Mild Reagent for the Transformation of 6-Nitro-Δ5-steroids to 5α-Hydroxy-6-ketosteroids

DOI: 10.1039/c39900000498

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 498 - 499 (1990)

Update date:2022-08-05

Topics:

Authors:

Singhal, Gireesh M.

Das, Nalin B.

Sharma, Ram P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900000498

Reaction of excess hydrated tin(II) chloride with 6-nitro-Δ⁵-steroids (1a-g) and (5) in tetrahydrofuran furnishes 5α-hydroxy-6-ketosteroids (2a-g) and (6) respectively, in good yields.

Full text of DOI:10.1039/c39900000498

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Z-mandelaldoxime

Cas No:129171-02-4

R&D Labs maybe for 129171-02-4

Naturalin Bio-Resource Co., Ltd

website:http://www.naturalin.com

Contact:+86-0731-84430651

Address:B1-402, Lu-Valley Enterprise Square.No.27 Wenxuan Road. Lu-Valley Hi-Tech District.
HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
Arshine Pharmaceutical Co., Limited

website:http://www.cnarshine.com

Contact:0731-88503671

Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China
Xi'an yuanfar international trade company

website:https://www.yuanfarchemical.com

Contact:86-029-88745613 ext 828

Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China

Relevant to this article

A novel preparation of thiazolo[5,4-c]pyridines and the synthesis of some imidazo[5,4-c]pyridines and oxazolo[4,5-c] pyridines

Doi:10.1002/jhet.5570270316
(1990)
Discovery of 1-[2-(2,4-Dimethylphenylsulfanyl)phenyl]piperazine (Lu AA21004): A Novel Multimodal Compound for the Treatment of Major Depressive Disorder

Doi:10.1021/jm101459g
(2011)
Selective catalytic hydrogenation of an olefin moiety in the presence of a terminal alkyne function

Doi:10.1016/0040-4039(90)80166-J
(1990)
ORTHO LITHIATION DIRECTED BY AMINO GROUPS ON SILICON IN PHENYLSILANE DERIVATIVES

Doi:10.1016/0040-4039(90)80186-P
(1990)
Two new antibiotics from the Red Sea sponge Psammaplysilla purpurea. Total ¹³C-NMR line assignment of psammaplysins A and B and aerothionin

Doi:10.1016/S0040-4020(01)91843-5
(1983)
Doi:10.1016/S0020-1693(00)80734-3
(1984)

Article Doi