Tin(II) Chloride Dihydrate - a Mild Reagent for the Transformation of 6-Nitro-Δ5-steroids to 5α-Hydroxy-6-ketosteroids

DOI: 10.1039/c39900000498

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 498 - 499 (1990)

Update date:2022-08-05

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Authors:

Singhal, Gireesh M.

Das, Nalin B.

Sharma, Ram P.

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Article abstract of DOI:10.1039/c39900000498

Reaction of excess hydrated tin(II) chloride with 6-nitro-Δ⁵-steroids (1a-g) and (5) in tetrahydrofuran furnishes 5α-hydroxy-6-ketosteroids (2a-g) and (6) respectively, in good yields.

Full text of DOI:10.1039/c39900000498

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