Journal of Organic Chemistry p. 4345 - 4349 (1989)
Update date:2022-09-26
Topics:
Keck, Gary E.
Cressman, Erik N. K.
Enholm, Eric J.
Syntheses of (+/-)-isoretronecanol, (+/-)-supinidine, (-)-dihydroxyheliotridane, and (+)-heliotridine are detailed.The key step in each case involves an intramolecular acyliminium ion cyclization onto a suitably positioned allylstannane for construction o
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