Surrogates for Chiral Aminomalondialdehyde. Synthesis of N-(9-Phenylfluoren-9-yl)serinal and N-(9-Phenylfluoren-9-yl)vinylglycinal

DOI: 10.1021/jo00277a016

Source and publish data:

Journal of Organic Chemistry p. 3824 - 3831 (1989)

Update date:2022-08-05

Topics: Chiral Optically pure Surrogate Enantiomeric purity

Authors:

Lubell, William

Rapoport, Henry

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Article abstract of DOI:10.1021/jo00277a016

The cyclic carbamate of N-(9-phenylfluoren-9-yl)serinal (5) and N-(9-phenylfluoren-9-yl)aminomalondialdehyde mono(dimethyl acetal) (16) were prepared from L-serine.Exposure to silica and nonnucleophilic base and treatment in Wittig coupling reactions proc

Full text of DOI:10.1021/jo00277a016

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