Additions of Chiral Allyltitanocenes to Aldehydes: Diastereoselective Synthesis of Homoallylic Alcohols with a Recyclable Chiral Transition Metal Reagent

DOI: 10.1021/jo00278a031

Source and publish data:

Journal of Organic Chemistry p. 4154 - 4158 (1989)

Update date:2022-09-26

Topics:

Authors:

Collins, Scott

Kuntz, Bradley A.

Hong, Yaping

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00278a031

Homochiral allyl- and crotyltitanocenes 4a (R = H) and 4b (R = Me) prepared from ansa-titanocene dichloride 2 react with aldehydes to provide on workup homoallylic alcohols 5 in excellent yield and with moderate to excellent anti diastereoselectivity in t

Full text of DOI:10.1021/jo00278a031

Products guided by the article

Product name:(3,5-Dinitro-phenyl)-carbamic acid (S)-1-phenyl-but-3-enyl ester

Cas No:122293-79-2

R&D Labs maybe for 122293-79-2

Weifang Adde Economic And Trade Co.,LTD.

Contact:86-536-8885548

Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED

Contact:+86-0532-82683616

Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China
Shanghai Taibao Pharmaceutical Technology Co., Ltd(expird)

Contact:021-52217366

Address:shanghai
ZHIJIANG ZENVA SINO COMMERCE AND TRADE CO., LTD.

website:http://www.zenvasino.com

Contact:+86-138-72658998

Address:Shibeishan Road,Zhijiang, Hubei, China

Relevant to this article

Dipolar compounds containing fluorene and a heteroaromatic ring as the conjugating bridge for high-performance dye-sensitized solar cells

Doi:10.1002/chem.200903151
(2010)
Construction of C(sp²)?C(sp³) Bond between Quinoxalin-2(1H)-ones and N-Hydroxyphthalimide Esters via Photocatalytic Decarboxylative Coupling

Doi:10.1002/asia.201900904
(2019)
Protein knockdown using methyl bestatin-ligand hybrid molecules: Design and synthesis of inducers of ubiquitination-mediated degradation of cellular retinoic acid-binding proteins

Doi:10.1021/ja100691p
(2010)
Enantioselective total synthesis of 9S-dihydroerythronolide A seco acid

Doi:10.1021/ja00198a041
(1989)
Transition-metal-free formal sonogashira coupling and α-carbonyl arylation reactions

Doi:10.1002/chem.200902911
(2010)
Two new types of π-conjugation between a fullerene sphere and an addend

Doi:10.1039/b920339g
(2010)

Article Doi