Additions of Chiral Allyltitanocenes to Aldehydes: Diastereoselective Synthesis of Homoallylic Alcohols with a Recyclable Chiral Transition Metal Reagent

DOI: 10.1021/jo00278a031

Source and publish data:

Journal of Organic Chemistry p. 4154 - 4158 (1989)

Update date:2022-09-26

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Authors:

Collins, Scott

Kuntz, Bradley A.

Hong, Yaping

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Article abstract of DOI:10.1021/jo00278a031

Homochiral allyl- and crotyltitanocenes 4a (R = H) and 4b (R = Me) prepared from ansa-titanocene dichloride 2 react with aldehydes to provide on workup homoallylic alcohols 5 in excellent yield and with moderate to excellent anti diastereoselectivity in t

Full text of DOI:10.1021/jo00278a031

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