Additions of Chiral Allyltitanocenes to Aldehydes: Diastereoselective Synthesis of Homoallylic Alcohols with a Recyclable Chiral Transition Metal Reagent

DOI: 10.1021/jo00278a031

Source and publish data:

Journal of Organic Chemistry p. 4154 - 4158 (1989)

Update date:2022-09-26

Topics:

Authors:

Collins, Scott

Kuntz, Bradley A.

Hong, Yaping

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00278a031

Homochiral allyl- and crotyltitanocenes 4a (R = H) and 4b (R = Me) prepared from ansa-titanocene dichloride 2 react with aldehydes to provide on workup homoallylic alcohols 5 in excellent yield and with moderate to excellent anti diastereoselectivity in t

Full text of DOI:10.1021/jo00278a031

Products guided by the article

Product name:(3,5-Dinitro-phenyl)-carbamic acid (S)-1-phenyl-but-3-enyl ester

Cas No:122293-79-2

R&D Labs maybe for 122293-79-2

LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District
Anhui Charm Imp.&Exp.Co., Ltd

website:http://www.chinacharm.cn/

Contact:86 551 5316260

Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China

Relevant to this article

Dipolar compounds containing fluorene and a heteroaromatic ring as the conjugating bridge for high-performance dye-sensitized solar cells

Doi:10.1002/chem.200903151
(2010)
Construction of C(sp²)?C(sp³) Bond between Quinoxalin-2(1H)-ones and N-Hydroxyphthalimide Esters via Photocatalytic Decarboxylative Coupling

Doi:10.1002/asia.201900904
(2019)
Protein knockdown using methyl bestatin-ligand hybrid molecules: Design and synthesis of inducers of ubiquitination-mediated degradation of cellular retinoic acid-binding proteins

Doi:10.1021/ja100691p
(2010)
Enantioselective total synthesis of 9S-dihydroerythronolide A seco acid

Doi:10.1021/ja00198a041
(1989)
Transition-metal-free formal sonogashira coupling and α-carbonyl arylation reactions

Doi:10.1002/chem.200902911
(2010)
Two new types of π-conjugation between a fullerene sphere and an addend

Doi:10.1039/b920339g
(2010)

Article Doi