THE INTRAMOLECULAR DIELS-ALDER CYCLOADDITION OF N-DIENOYL ACRYLIMIDATES. NEW METHODOLOGY FOR THE CONSTRUCTION OF NITROGEN HETEROCYCLES

DOI: 10.1016/S0040-4039(00)85076-5

Source and publish data:

Tetrahedron Letters p. 4837 - 4840 (1986)

Update date:2022-08-05

Topics:

Authors:

Shea, K.J.

Svoboda, J.J.

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Article abstract of DOI:10.1016/S0040-4039(00)85076-5

N-(3,5-Hexadienoyl)-acrylimiates, which have been synthesized by acylation of 2-ethoxy-1-aza-1,3-butadienes with 3,5-hexadienoyl chloride, are found to undergo facile intramolecular Diels-Alder cycloadditions to afford predominately cis-hexahydroisoquinolines in good yields.

Full text of DOI:10.1016/S0040-4039(00)85076-5

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