Chemistry Letters p. 177 - 178 (1997)
Update date:2022-07-31
Topics:
Tatsugi, Jiro
Hara, Tomoaki
Izawa, Yasuji
Irradiation of indane-1,2,3-trione in degassed alcoholic solutions affords 3-alkoxycarbonylphthalides as the major product together with 3-alkoxyphthalides. 3-Alkoxycarbonylphthalides may be derived from the reaction between alcohols and the spirooxiranone intermediate, generated photochemically by cleavage of the bond between two carbonyl groups of indane-1,2,3-trione via a cyclobutenone biradical derivative.
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