A facile synthetic route to (η5-benzoylcyclopentadienyl)metal compounds

DOI: 10.1016/0022-328X(93)80132-U

Source and publish data:

Journal of Organometallic Chemistry p. 27 - 31 (1993)

Update date:2022-08-04

Topics:

Authors:

Jones, Stephen S.

Rausch, Marvin D.

Bitterwolf, Thomas E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(93)80132-U

A reaction between cyclopentadienylsodium and ethyl benzoate in refluxing THF produces (benzoylcyclopentadienyl)sodium (4) in 70-80percent yield.Subsequent treatment of 4 in ethanol solution with thallium ethoxide affords (benzoylcyclopentadienyl)thallium (3) in nearly quantitative yield.Reactions of 3 with Mn(CO)5Br, Re(CO)5Br, 2 or FeCl2 lead to the respective η⁵-benzoylcyclopentadienyl derivatives of these metals, and demonstrate the utility of 3 in organometallic syntheses.Reactions of several of these organometallic ketones with cymantrenyllithium<(η⁵-C5H4Li)Mn(CO)3> provide a useful new route to bimetallic compounds.

Full text of DOI:10.1016/0022-328X(93)80132-U

Products guided by the article

Product name:(η5-C5H4(COPh))Re(CO)3

Cas No:12267-07-1

R&D Labs maybe for 12267-07-1

Zhejiang Sanmei Chemical Industry Co., Ltd

Contact:86-579-87633213

Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Hangzhou Sartort Biopharma Co., Ltd

website:http://www.sartort.com

Contact:86-571-87039693

Address:No. 57, Tech Park Road, Hangzhou, Zhejiang, China
Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China

Relevant to this article

Mild and efficient reductive deoxygenation of epoxides to olefins with tin(II) chloride/sodium iodide as a novel reagent

Doi:10.1055/s-0034-1378821
(2015)
Synthesis of N-(tert-Butyloxycarbonyl)-CBI, CBI, CBI-CDPI₁, and CBI-CDPI₂: Enhanced Functional Analogues of CC-1065 Incorporating the 1,2,9,9a-Tetrahydrocyclopropabenzindol-4-one (CBI) Left-Hand Subunit

Doi:10.1021/jo00310a013
(1990)
Synthesis of the repeating unit of the lipoteichoic acid of Streptococcus pneumoniae

Doi:10.1016/j.tet.2011.11.088
(2012)
Palladium complexes with a tridentate PNO ligand. Synthesis of η¹-allyl complexes and cross-coupling reactions promoted by boron compounds

Doi:10.1039/b913130b
(2010)
Synthesis of a succinate-dihydrotestosterone-dihydropyrimidine conjugate

Doi:10.1007/s00706-009-0223-6
(2010)
High-generation second-order nonlinear optical (NLO) dendrimers: Convenient synthesis by click chemistry and the increasing trend of nlo effects

Doi:10.1002/anie.200906946
(2010)

Article Doi