Chirality control by substituents in the asymmetric addition of Et2Zn to aromatic aldehydes catalyzed by cis-(1R,2S)-2-benzamidocyclohexanecarboxylic acid derived 1,3-aminoalcohols

DOI: 10.1002/cjoc.201090036

Source and publish data:

Chinese Journal of Chemistry p. 61 - 68 (2010)

Update date:2022-07-30

Topics:

Authors:

Wang, Xiangbo

Kodama, Koichi

Hirose, Takuji

Zhang, Guangyou

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Article abstract of DOI:10.1002/cjoc.201090036

A series of novel optically active 1,3-aminoalcohols based on cis-(1R,2S)-2-benzamidocyclohexanecarboxylic acid and trans-(1R,2R)-2-benzamidocyclohexanecarboxylic acid were synthesized and used in the asymmetric diethylzinc addition to aromatic aldehydes.

Full text of DOI:10.1002/cjoc.201090036

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Product name:(1R,2S)-2-benzamidocyclohexanecarboxylate

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