Chemical Communications p. 2656 - 2658 (2010)
Update date:2022-08-05
Topics:
Sonawane, Manoj R.
Cisaova, Ivana
Lyapkalo, Ilya M.
(E)-N-Trimethylsilyloxyenamines, easily accessible from aldonitrones, proved to be excellent nucleophiles in TMSOTf-induced diastereoselective aldol reaction, both with ketals and acetals, proceeding via an extended transition state and leading to a new aldol C-C-bond in the aldonitrone products, that can be readily hydrolysed to the corresponding aldehydes.
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Doi:10.1016/j.bmcl.2010.02.084
(2010)Doi:10.1021/ic1001732
(2010)Doi:10.1055/s-1989-27244
(1989)Doi:10.1016/j.bmcl.2010.02.047
(2010)Doi:10.1021/jm00132a007
(1989)Doi:10.1016/j.bmc.2010.02.040
(2010)