Hemilabile P-alkene ligands in chiral rhodium and copper complexes: Catalytic asymmetric 1,4 additions to enones. 2

DOI: 10.1021/om100248u

Source and publish data:

Organometallics p. 2503 - 2514 (2010)

Update date:2022-08-04

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Authors:

Dorta, Romano

Drinkel, Emma

Briceno, Alexander

Dorta, Reto

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Article abstract of DOI:10.1021/om100248u

Two equivalents of the chiral dibenz[b,f]azepine-derived P-alkene ligands 2-6 per metal afforded mononuclear Rh(I) and Cu(I) complexes that were used as catalysts for asymmetric conjugate addition reactions. Rh formed square-planar neutral (8-10) and cati

Full text of DOI:10.1021/om100248u

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