Studies on the Mechanism of the Asymmetric Epoxidation: A Ligand Variation Approach

DOI: 10.1021/jo00278a004

Source and publish data:

Journal of Organic Chemistry p. 4016 - 4018 (1989)

Update date:2022-08-02

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Authors:

Carlier, Paul R.

Sharpless, K. Barry

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Article abstract of DOI:10.1021/jo00278a004

The application of linked bis-tartrate esters as ligands for the titanium-mediated asymmetric epoxidation is studied in order to gain information about the structure of the active catalytic species.The results obtained argue against the sole intermediacy of monomeric titanium-tartrate in the parent system.

Full text of DOI:10.1021/jo00278a004

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