Thermal Oxidative Deamination of Aliphatic Amines to Aldehydes with Bis(diphenylphosphinyl) Peroxide

DOI: 10.1055/s-1988-27750

Source and publish data:

Synthesis p. 907 - 910 (1988)

Update date:2022-08-04

Topics:

Authors:

Masse, Guy

Sturtz, Georges

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Article abstract of DOI:10.1055/s-1988-27750

Reaction of N-substituted alkylamines having pseudoacidic hydrogen at the 1-methylene group with bis(diphenylphosphinyl) peroxide yields the deaminated products by thermal elimination of diphenylphosphinic acid from the intermediate O-diphenylphosphinylhydroxylamines.

Full text of DOI:10.1055/s-1988-27750

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