Remarkably Facile 1,3-Diol Fragmentation. Synthesis of a Seco-sesquiterpene of Tobacco

DOI: 10.1246/cl.1989.61

Source and publish data:

Chemistry Letters p. 61 - 64 (1989)

Update date:2022-07-31

Topics:

Authors:

Kato, Michiharu

Tooyama, Youichi

Yoshikoshi, Akira

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Article abstract of DOI:10.1246/cl.1989.61

A benzylic hydroxyl group activated by the 2,6-dimethoxy-4-methylphenyl group was proved to be a remarkably reactive nucleofuge in 1,3-diol fragmentation under mild conditions. 4-(2,2,6-Trimethyl-6-vinylcyclohexyl)-2-butanone, a seco-sesquiterpene, was sy

Full text of DOI:10.1246/cl.1989.61

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