SYNTHESIS OF exo and endo-BREVICOMIN VIA THE RHODIUM ACETATE CATALYZED CYCLOADDITION REACTION OF 1-DIAZO-2,5-HEXANEDIONE

DOI: 10.1016/S0040-4039(00)99499-1

Source and publish data:

Tetrahedron Letters p. 1491 - 1494 (1989)

Update date:2022-08-05

Topics:

Authors:

Padwa, Albert

Chinn, Richard L.

Zhi, Lin

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Article abstract of DOI:10.1016/S0040-4039(00)99499-1

Treatment of 1-diazo-2,5-hexanedione with rhodium (II) acetate in the presence of various aldehydes affords the 6,8-dioxabicyclo<3.2.1>octane ring system in high yield.

Full text of DOI:10.1016/S0040-4039(00)99499-1

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