The Effects of cis-Coordinating Phosphine of Chiral Bisphosphine-Rhodium Complexes on the Catalytic Activities in the Asymmetric Hydrogenation of Itaconic Acid

DOI: 10.1246/cl.1999.559

Source and publish data:

Chemistry Letters p. 559 - 562 (1989)

Update date:2022-09-26

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Authors:

Takahashi, Hisashi

Yamamoto, Naoko

Takeda, Hideo

Achiwa, Kazuo

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Article abstract of DOI:10.1246/cl.1999.559

The effects of cis-coordinating phosphine of the rhodium complexes of BCPM ((2S,4S)-N-(t-butoxycarbonyl)-4-(dicyclohexylphosphino)-2-<(diphenylphosphino)methyl>pyrrolidine) analogues bearing electron donating or attracting groups on the catalytic activities in the asymmetric hydrogenation of itaconic acid are described.

Full text of DOI:10.1246/cl.1999.559

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