Tetrahedron Letters p. 2217 - 2220 (1989)
Update date:2022-08-03
Topics:
Auge, Claudine
Bouxom, Benedicte
Cavaye, Bertrand
Gautheron, Christine
New substrates have been used in the aldol condensation catalyzed by immobilized acylneuraminate pyruvate lyase: hexoses 3, 4, 7, 8 and pentoses 2, 5, 6.Condensation of pyruvate with 2-5, 7 and 8 led to pure compounds related to 3-deoxy-D-glycero-D-galacto-nonulosonic acid (KDN).Surprisingly, condensation with D-arabinose 6 gave a mixture of diastereomers, 3-deoxy-α-D-manno-2-octulosonic acid (KDO) and 4-epi KDO.
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