SCOPE AND LIMITATIONS OF THE ALDOL CONDENSATION CATALYZED BY IMMOBILIZED ACYLNEURAMINATE PYRUVATE LYASE

DOI: 10.1016/S0040-4039(00)99652-7

Source and publish data:

Tetrahedron Letters p. 2217 - 2220 (1989)

Update date:2022-08-03

Topics:

Authors:

Auge, Claudine

Bouxom, Benedicte

Cavaye, Bertrand

Gautheron, Christine

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Article abstract of DOI:10.1016/S0040-4039(00)99652-7

New substrates have been used in the aldol condensation catalyzed by immobilized acylneuraminate pyruvate lyase: hexoses 3, 4, 7, 8 and pentoses 2, 5, 6.Condensation of pyruvate with 2-5, 7 and 8 led to pure compounds related to 3-deoxy-D-glycero-D-galacto-nonulosonic acid (KDN).Surprisingly, condensation with D-arabinose 6 gave a mixture of diastereomers, 3-deoxy-α-D-manno-2-octulosonic acid (KDO) and 4-epi KDO.

Full text of DOI:10.1016/S0040-4039(00)99652-7

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