TANDEM ORGANOMETALLIC ADDITION REACTIONS TO N-METHOXY-UREAS AND URETHANES IN THE PREPARATION OF UNSYMMETRICAL AND SYMMETRICAL KETONES

DOI: 10.1016/S0040-4039(00)99576-5

Source and publish data:

Tetrahedron Letters p. 1773 - 1776 (1989)

Update date:2022-08-06

Topics:

Authors:

Hlasta, Dennis J.

Court, John J.

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Article abstract of DOI:10.1016/S0040-4039(00)99576-5

The use of novel reagents 1a-c for the synthesis of ketones in a one pot reaction is described.An interesting leaving group effect was discovered in the fragmentation of the proposed complexes 2 to the intermediate N-methoxyamides 3.

Full text of DOI:10.1016/S0040-4039(00)99576-5

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