On the Direct Formation of Episulfonium Ions from Alkenes. An Application to the Synthesis of Higher Order Carbocycles via Episulfonium Ion Initiated Polyene Cyclizations

DOI: 10.1021/jo00381a049

Source and publish data:

Journal of Organic Chemistry p. 949 - 951 (1987)

Update date:2022-07-31

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Authors:

Edstrom, Eric D.

Livinghouse, Tom

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Article abstract of DOI:10.1021/jo00381a049

The use of methyl benzenesulfenate-Lewis acid binary systems for effecting biomimetic polyene cyclizations initiated by episulfonium ions has been demonstrated.The efficiency of higher order annulation is related to the stereostructure of the polyene as w

Full text of DOI:10.1021/jo00381a049

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