Directed Metalation of Benzenesulfinamides. A Novel Route to Meta-Substituted Aromatic Compounds

DOI: 10.1021/jo00288a015

Source and publish data:

Journal of Organic Chemistry p. 74 - 78 (1990)

Update date:2022-08-05

Topics:

Authors:

Katritzky, Alan R.

Lue, Ping

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Article abstract of DOI:10.1021/jo00288a015

Directed lithiation ortho to the sulfinamide group of readily available ortho- and para-substituted N-phenylbenzenesulfinamides (5a-d) and reaction with a variety of electrophiles followed by mercuridesulfination (HgCl2) or dehydrodesulfination (Ra/Ni) co

Full text of DOI:10.1021/jo00288a015

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