Directed Metalation of Benzenesulfinamides. A Novel Route to Meta-Substituted Aromatic Compounds

DOI: 10.1021/jo00288a015

Source and publish data:

Journal of Organic Chemistry p. 74 - 78 (1990)

Update date:2022-08-05

Topics:

Authors:

Katritzky, Alan R.

Lue, Ping

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00288a015

Directed lithiation ortho to the sulfinamide group of readily available ortho- and para-substituted N-phenylbenzenesulfinamides (5a-d) and reaction with a variety of electrophiles followed by mercuridesulfination (HgCl2) or dehydrodesulfination (Ra/Ni) co

Full text of DOI:10.1021/jo00288a015

Products guided by the article

Product name:4-Chloro-2-methylbenzenesulfinanilid

Cas No:123858-19-5

R&D Labs maybe for 123858-19-5

Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
ANGCHEN BRIGHTCHEM CO., LTD

website:http://www.angchenchem.com

Contact:+86-510-88302099 82327577

Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China
Changsha Yihai Chemical Technology Co.,ltd

website:http://www.cs-yihai.com/

Contact:0731- 85620465

Address:Room 23005, unit 2, the northern building of Xiangsong international building , NO.259 Shaoshan Road , Changsha , Hunan, China.(mainland)
Jintan City Mego Chemical Co., Ltd

Contact:+86-0519-82814387

Address:23# Dengguan Town, Jintan, Jiangsu Province, China
Sanming Coffer Fine Chemical Industrial Co., Ltd

website:http://www.cofferxm.com/

Contact:+86-598-5853979

Address:Jin-sha Yuan Chuang-ye Park,Hi-Tech Development Zone,Sanming City P.R.China

Relevant to this article

Catalytic enantioselective synthesis of sterically demanding alcohols using di(2°-alkyl)zinc prepared by the refined Charette's method

Doi:10.1039/c0cc01301c
(2010)
Palladium-catalyzed (N-oido-2-pyridinyl)methyl transfer from 2-(2-Hydroxyalkyl)pyridine N-oxide to aryl halides by β-carbon elimination

Doi:10.1002/asia.200900151
(2009)
Isoform-selective thiazolo[5,4-b]pyridine S1P₁ agonists possessing acyclic amino carboxylate head-groups

Doi:10.1016/j.bmcl.2011.12.073
(2012)
The First Direct Chlorination of Iodoarenes - A Side-chain Directed Process

Doi:10.1055/s-2003-42412
(2003)
Amberlyst-15 catalysed synthesis of N-tosyl-α-aminonitriles through Strecker reaction

Doi:10.3184/030823409X12611577711291
(2010)
Photoredox Oxo-C(sp³)-H Bond Functionalization via in Situ Cu(I)-Acetylide Catalysis

Doi:10.1021/acs.orglett.9b04277
(2020)

Article Doi