Tetrahedron p. 4091 - 4100 (1990)
Update date:2022-08-02
Topics:
Bertz, Steven H.
Smith, Robin A. J.
The influence of silanes on the reaction of enones with cuprates has been examined using the title enone compound and Me2CuLi.LiI. In ether solvent the effect the effect of various silanes on the 1,4/1,2 addition ratio was minor. In tetrahydrofuran significantly increased 1,4/1,2 addition ratios and increased conversion of substrate was noted in the presence of silanes. Me3SiCl proved to be the most effective of the silanes examined for preferential 1,4 enone addition.
View MoreContact:86-571-87758773
Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Tai zhou world Pharm & Chem Co., Ltd
Contact:+86-576-85301198
Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
website:http://www.oceanchem-group.com
Contact:86-536-8596048
Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Chemvon Biotechnology Co. Ltd.
website:http://www.chemvon.com
Contact:86-21-58550039;86-21-31268550-8004
Address:Suite B-10#, 6999 Chuansha Road, Pudong District, Shanghai 201202, China
website:http://www.lonwinchem.com
Contact:Tel: 86-21-59858395
Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
Doi:10.1002/ardp.200900279
(2010)Doi:10.1016/j.polymer.2010.05.044
(2010)Doi:10.1021/jo00079a042
(1993)Doi:10.1016/j.tetasy.2010.04.021
(2010)Doi:10.1016/j.tetasy.2010.04.047
(2010)Doi:10.1002/chir.23038
(2019)
