Base-Induced and -Directed Rearrangements of 4-Monotosylated Perhydronaphthalene-1,4-diols. Synthesis of (+/-)-5-epi-Nardol

DOI: 10.1021/jo00290a027

Source and publish data:

Journal of Organic Chemistry p. 941 - 948 (1990)

Update date:2022-07-31

Topics:

Authors:

Wijnberg, Joannes B. P. A.

Jenniskens, Louis H. D.

Brunekreef, Gerd A.

Groot, Aede de

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Article abstract of DOI:10.1021/jo00290a027

The utility of perhydronaphthalene precursors for the synthesis of sesquiterpenes which possess a cis-fused perhydroazulene skeleton with an exocyclic methylene unit has been examined.For this purpose the tosylates 3, 4, 28, and 29 were prepared, and thei

Full text of DOI:10.1021/jo00290a027

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Product name:(4'aα,5'α,8'aβ)-octahydro-4'a-methylspiro<1,3-dioxolane-2,2'(1'H)-naphthalene>-5'-ol 5'-(4-methylbenzenesulfonate)

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