REGIOSELECTIVE ALKYLATION OF DIANIONS OF CYCLIC 1,3-DIKETONES VIA THEIR MONODIMETHYLHYDRAZONES. SYNTHESIS OF C-4 SUBSTITUTED 1,3-DIKETONES

DOI: 10.1016/S0040-4039(00)99560-1

Source and publish data:

Tetrahedron Letters p. 1705 - 1708 (1989)

Update date:2022-09-26

Topics:

Authors:

Demir, Ayhan S.

Enders, Dieter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)99560-1

Cyclic 1,3-diketones are transformed into the corresponding monodimethylhydrazones, which can be alkylated regioselectively at C-4 via dianions with various alkyl halides.

Full text of DOI:10.1016/S0040-4039(00)99560-1

Products guided by the article

Product name:3-(N',N'-Dimethyl-hydrazino)-4-methyl-cyclohex-2-enone

Cas No:124015-80-1

R&D Labs maybe for 124015-80-1

SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone
Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
Qingdao Pana-Life Biochem Co.,Ltd.

Contact:86-532-87683902

Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021

Relevant to this article

Synthesis and structure-activity relationships of indazole arylsulfonamides as allosteric CC-chemokine receptor 4 (CCR4) antagonists

Doi:10.1021/jm301572h
(2013)
Living 3,4-polymerization of isoprene by cationic rare earth metal alkyl complexes bearing iminoamido ligands

Doi:10.1021/om100971d
(2011)
L,3-Bis(trimethylsilyl)-l,3,2-diazaphospha-[3]ferrocenophanes

Doi:10.1002/zaac.200900494
(2010)
Access to Imidazo[1,2-a]pyridines via Annulation of α-Keto Vinyl Azides and 2-Aminopyridines

Doi:10.1021/acs.orglett.5b02124
(2015)
Transformation of α- and β-Ionones into α- and β-Damascone and β-Damascenone Using Allylsilane Chemistry

Doi:10.1021/jo00290a057
(1990)
Multicatalytic one-pot reaction of 1-(2-alkynylphenyl)ketoximes for generation of indole derivatives

Doi:10.1021/ol101487q
(2010)

Article Doi