SELECTIVE AND STEREOCONTROLLED HYDROBORATION OF 13-EPI-PIMARADIENE DITERPENOIDS

DOI: 10.1016/S0040-4020(01)80046-6

Source and publish data:

Tetrahedron p. 1815 - 1822 (1989)

Update date:2022-09-26

Topics:

Authors:

San Felicianio, Arturo

Medarde, Manuel

Tome, Fernando

Caballero, Esther

Hebrero, Belen

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80046-6

By introduction of bulky substituents at C₁₆ it has been possible to achieve the stereoselective β-hydroboration-oxidation of the Δ⁸⁽¹⁴⁾ double bond in 13-epi-pimarane diterpenoids.

Full text of DOI:10.1016/S0040-4020(01)80046-6

Products guided by the article

Product name:methyl 16-tert-butyldiphenylsyloxy-13-epi-pimar-8⁽¹⁴⁾-en-18-oate

Cas No:124062-64-2

R&D Labs maybe for 124062-64-2

Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Xi'an Galaxy Chemicals CO., Ltd

Contact:86-29-89380370

Address:No.8, Gaoxin three road, Xi'an city.
Jiangxi Biochem Co.,Ltd

Contact:86-791-86629460

Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China
Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China

Relevant to this article

Experimental and DFT ¹H NMR study of conformational equilibria in trans-4′,7-dihydroxyisoflavan-4-ol and trans-isoflavan-4-ol

Doi:10.1021/jo0301200
(2003)
A Total Synthesis of the Racemic Sesquiterpene Parvifoline

Doi:10.1021/jo972092p
(1998)
Domino approach for the synthesis of pyrrolo[1,2-α]pyrazine from vinyl azides

Doi:10.1021/ol101538x
(2010)
Chiral zirconium complex as bronsted base catalyst in asymmetric directtype mannich reactions

Doi:10.1002/asia.200900524
(2010)
1,3-dicyclohexylimidazol-2-ylidene as a superior ligand for the nickel-catalyzed cross-couplings of aryl and benzyl methyl ethers with organoboron reagents

Doi:10.1021/ol502583h
(2014)
Doi:10.1021/jo01105a039
(1958)

Article Doi