SELECTIVE AND STEREOCONTROLLED HYDROBORATION OF 13-EPI-PIMARADIENE DITERPENOIDS

DOI: 10.1016/S0040-4020(01)80046-6

Source and publish data:

Tetrahedron p. 1815 - 1822 (1989)

Update date:2022-09-26

Topics:

Authors:

San Felicianio, Arturo

Medarde, Manuel

Tome, Fernando

Caballero, Esther

Hebrero, Belen

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)80046-6

By introduction of bulky substituents at C₁₆ it has been possible to achieve the stereoselective β-hydroboration-oxidation of the Δ⁸⁽¹⁴⁾ double bond in 13-epi-pimarane diterpenoids.

Full text of DOI:10.1016/S0040-4020(01)80046-6

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