One-pot Synthesis of 2-Aryloxymethyl-1-cyanomethyl-5,6-dihydro-4H-pyrroloquinoline via Rearrangement of the N-Oxide from 1-Aryloxy-4-tetrahydro-1-quinolylbut-2-yne

DOI: 10.1039/P19890001285

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1285 - 1288 (1989)

Update date:2022-08-05

Topics: Rearrangement one-pot synthesis N-oxide

Authors:

Majumdar, Krishna C.

Chattopadhyay, Shital K.

Khan, Abu T.

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Article abstract of DOI:10.1039/P19890001285

1-Aryloxy-4-tetrahydro-1-quinolylbut-2-yne (1), on treatment with m-chloroperbenzoic acid in dichloromethane at room temperature for 12 h, rearranged to give the bispyrroloquinoline derivative (3) in 30-45percent yield.Addition of aqueous potassium cyanid

Full text of DOI:10.1039/P19890001285

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Product name:1-[4-(2-Chloro-phenoxy)-but-2-ynyl]-1,2,3,4-tetrahydro-quinoline

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