LITHIUM DISELENIDE IN APROTIC MEDIUM - A CONVENIENT REAGENT FOR SYNTHESIS OF ORGANIC DISELENIDES

DOI: 10.1016/S0040-4020(01)89801-X

Source and publish data:

Tetrahedron p. 6119 - 6130 (1988)

Update date:2022-08-04

Topics:

Authors:

Syper, Ludwik

Mlochowski, Jacek

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Article abstract of DOI:10.1016/S0040-4020(01)89801-X

The reduction of selenium with lithium in THF in the presence of diphenylacetylene as a catalyst afforded lithium diselenide, which reacted with electrophiles giving alkyl or aryl diselenides 1 - 3 and selenides 4, as by-products.The useful method for preparation of diselenides based on this reaction was elaborated.

Full text of DOI:10.1016/S0040-4020(01)89801-X

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