Enantioselective epoxidation of unfunctionalized simple olefins by non-racemic molybdenum(VI)(oxo-diperoxo) complexes

DOI: 10.1016/0022-328X(89)87277-8

Source and publish data:

Journal of Organometallic Chemistry p. 81 - 96 (1989)

Update date:2022-07-30

Topics:

Authors:

Schurig, V.

Hintzer, K.

Leyrer, U.

Mark, C.

Pitchen, P.

Kagan, H. B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(89)87277-8

Molybdenum(VI)(oxo-diperoxo) complexes bearing bidentate ligands with hydroxy and carbonyl functions show asymmetric induction in the stoichiometric epoxidation of simple prochiral olefins.The influence of the ligand and alkene structure on the enantiomeric excess of the oxiranes has been investigated.The addition of chiral diols to the molybdenum(VI)(oxo-diperoxo) reagents gives high enantiomeric excesses probably because of an efficient kinetic resolution of the oxiranes formed.

Full text of DOI:10.1016/0022-328X(89)87277-8

Products guided by the article

Product name:(S)-3-benzyloxybutanoic acid piperidineamide

Cas No:124558-79-8

R&D Labs maybe for 124558-79-8

Melone Pharmaceutical Co., ltd

Contact:+86-411 82593920, 82593631

Address:No 232, JInma Roda, Development Zone, Dalian, China
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD

Contact:+86-25-86883560 15951806178

Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD

Contact:+86-22-25210964

Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China
Taizhou KEDE Chemical.Co.,Ltd.

Contact:86-576-84613060

Address:Jiangkou Chemical Zoon
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town

Relevant to this article

Helical Oligopeptides of a Quaternized Amino Acid with Tunable Chiral-Induction Ability and an Anomalous pH Response

Doi:10.1002/chem.201605460
(2017)
Synthesis of γ-functionalized allyltrichlorosilanes and their application in the asymmetric allylation of aldehydes

Doi:10.1016/j.tetasy.2010.03.026
(2010)
Steroidal A ring aryl carboxylic acids: A new class of steroid 5α-reductase inhibitors

Doi:10.1021/jm00165a009
(1990)
Total Synthesis of Dictyodendrins by the Gold-Catalyzed Cascade Cyclization of Conjugated Diynes with Pyrroles

Doi:10.1002/anie.201703279
(2017)
Anhydrotetracycline-peptide conjugates as representatives for ligand-based transactivating systems

Doi:10.1016/j.bmc.2010.06.061
(2010)
C-H activation of acetonitrile at nickel: Ligand flip and conversion of N-bound acetonitrile into a C-bound cyanomethyl ligand

Doi:10.1021/ja105368p
(2010)

Article Doi