Journal of Organometallic Chemistry p. 81 - 96 (1989)
Update date:2022-07-30
Topics:
Schurig, V.
Hintzer, K.
Leyrer, U.
Mark, C.
Pitchen, P.
Kagan, H. B.
Molybdenum(VI)(oxo-diperoxo) complexes bearing bidentate ligands with hydroxy and carbonyl functions show asymmetric induction in the stoichiometric epoxidation of simple prochiral olefins.The influence of the ligand and alkene structure on the enantiomeric excess of the oxiranes has been investigated.The addition of chiral diols to the molybdenum(VI)(oxo-diperoxo) reagents gives high enantiomeric excesses probably because of an efficient kinetic resolution of the oxiranes formed.
View MoreContact:027-87677569
Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
Tianjin Anda North Industrial & Business Co.Ltd.
Contact:86-22-24999306
Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
Contact:86-791-86629460
Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China
Shanghai Haoyuan Chemexpress Co., Ltd.
website:https://www.chemexpress.com/
Contact:86-21-58950125
Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Contact:+31-24-3886056
Address:Binderskampweg 29 Unit 36
Doi:10.1002/chem.201605460
(2017)Doi:10.1016/j.tetasy.2010.03.026
(2010)Doi:10.1021/jm00165a009
(1990)Doi:10.1002/anie.201703279
(2017)Doi:10.1016/j.bmc.2010.06.061
(2010)Doi:10.1021/ja105368p
(2010)