Journal of Organometallic Chemistry p. 81 - 96 (1989)
Update date:2022-07-30
Topics:
Schurig, V.
Hintzer, K.
Leyrer, U.
Mark, C.
Pitchen, P.
Kagan, H. B.
Molybdenum(VI)(oxo-diperoxo) complexes bearing bidentate ligands with hydroxy and carbonyl functions show asymmetric induction in the stoichiometric epoxidation of simple prochiral olefins.The influence of the ligand and alkene structure on the enantiomeric excess of the oxiranes has been investigated.The addition of chiral diols to the molybdenum(VI)(oxo-diperoxo) reagents gives high enantiomeric excesses probably because of an efficient kinetic resolution of the oxiranes formed.
View Moreshijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
Contact:+86 18616952870
Address:Area
Chengda Pharmaceuticals Co., Ltd.
Contact:+86-573-84601188
Address:hengshan Road 5# in Jiashan, zhejiang
Changzhou Litong Chemical Co., Ltd.
website:http://www.litonchem.com/
Contact:+86-519-86301238
Address:Laoba Rd, Hutang town Changzhou Jiangsu
Shanghai Hanshare Industry Co.,Ltd.
Contact:86 21 20960688
Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
Doi:10.1002/chem.201605460
(2017)Doi:10.1016/j.tetasy.2010.03.026
(2010)Doi:10.1021/jm00165a009
(1990)Doi:10.1002/anie.201703279
(2017)Doi:10.1016/j.bmc.2010.06.061
(2010)Doi:10.1021/ja105368p
(2010)
