isolate the product more quantitatively. The total yield of the
analytically pure compound is 0.84 g (67.7%). Anal. calc. for
C36H63I2InN3O2 C, 46.07; H, 6.77; I, 27.04, In, 12.23, N,
4.48%. Found: C, 46.28; H, 6.99; I, 26.90, In, 12.62, N, 4.31%.
IR (Nujol, KBr) cmꢂ1: 1587(m), 1562(w), 1520(w), 1436(s),
1361(s), 1354(s), 1335(m), 1319(m), 1255(s), 1227(w), 1216(w),
1199(m), 1179(w), 1169(m), 1112(m), 1101(m), 1057(w),
1041(w), 1026(w), 1008(w), 992(m), 965(w), 937(w), 911(m),
883(w), 872(m), 861(m), 819(w), 798(s), 778(w), 764(m),
743(w), 708(w), 666(w), 648(w), 638(w), 627(w), 607(w),
574(w), 539(w), 527(w).
Soc., Dalton Trans., 1998, 3543–3548; (h) M. A. Brown,
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3 (a) R. J. Baker, R. D. Farley, C. Jones, M. Kloth and
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X-Ray crystallographic study of 1–3
4 (a) G. A. Abakumov, A. I. Poddel’sky, E. V. Grunova,
V. K. Cherkasov, G. K. Fukin, Yu. A. Kurskii and
L. G. Abakumova, Angew. Chem., Int. Ed., 2005, 44, 2767–2771;
(b) V. K. Cherkasov, G. A. Abakumov, E. V. Grunova,
A. I. Poddel’sky, G. K. Fukin, E. V. Baranov, Yu. A. Kursky
and L. G. Abakumova, Chem.–Eur. J., 2006, 12, 3916–3927;
(c) P. Chaudhuri, E. Bill, R. Wagner, U. Pieper, B. Biswas and
Intensity data for 1–3 were collected at 100 K on a Bruker
Smart Apex diffractometer with graphite monochromated
Mo-Ka radiation (l = 0.71073 A) in the j–o scan mode
(o = 0.31, 10 s on each frame). The intensity data were integ-
rated by SAINT program.14 SADABS15 was used to perform
area-detector scaling and absorption corrections. The struc-
tures were solved by direct methods and were refined on F2
using all reflections with SHELXTL package.16 All non-
hydrogen atoms were refined anisotropically. The hydrogen
atoms were found from Fourier synthesis and refined iso-
tropically. The crystal data collection and structure refinement
data are listed in Table 2.
T. Weyhermuller, Inorg. Chem., 2008, 47, 5549–5551;
¨
(d) A. V. Piskunov, I. N. Mescheryakova, G. K. Fukin,
E. V. Baranov, M. Hummert, A. S. Shavyrin, V. K. Cherkasov
and G. A. Abakumov, Chem.–Eur. J., 2008, 14, 10085–10093.
5 G. A. Abakumov, V. K. Cherkasov, A. V. Piskunov,
I. N. Mescheryakova, A. V. Maleeva, A. I. Poddel’sky and
G. K. Fukin, Dokl. Chem., 2009, 427, 168–171.
6 (a) P. Chaudhuri, R. Wagner, U. Pieper, B. Biswas and
2008,
T.
Weyhermuller,
¨
Dalton
Trans.,
1286–1288;
(b) A. V. Piskunov, I. N. Mescheryakova, E. V. Baranov,
G. K. Fukin, V. K. Cherkasov and G. A. Abakumov, Russ. Chem.
Bull., 2010, 59, 361–370; (c) A. V. Piskunov, I. N. Mescheryakova,
G. K. Fukin, G. V. Romanenko, A. S. Bogomyakov,
V. K. Cherkasov and G. A. Abakumov, Heteroat. Chem., 2009,
20, 332–340; (d) A. V. Piskunov, I. A. Aivaz’yan, G. A. Abakumov,
V. K. Cherkasov, O. V. Kuznetsova, G. K. Fukin and
E. V. Baranov, Russ. Chem. Bull., 2007, 56, 261–266.
Acknowledgements
We are grateful to the Russian Foundation for Basic Research
(grant 10-03-00921), Russian President Grants (NSh-7065.2010.3,
MK-1286.2009.3) for financial support of this work.
7 (a) A. V. Piskunov, I. A. Aivaz’yan, G. K. Fukin, E. V. Baranov,
A. S. Shavyrin, V. K. Cherkasov and G. A. Abakumov, Inorg.
Chem. Commun., 2006, 9, 612–615; (b) A. V. Piskunov,
I. A. Aivaz’yan, A. I. Poddel’sky, G. K. Fukin, E. V. Baranov,
V. K. Cherkasov and G. A. Abakumov, Eur. J. Inorg. Chem., 2008,
1435–1444.
8 A. V. Piskunov, I. N. Mescheryakova, A. S. Bogomyakov,
G. V. Romanenko, V. K. Cherkasov and G. A. Abakumov, Inorg.
Chem. Commun., 2009, 12, 1067–1070.
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ꢀc
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