Synthesis of the Esperamicin A1/Calicheamicin γ-Trisulphide Functionality: Thermal Stability and Reduction

DOI: 10.1039/c39890000916

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 916 - 919 (1989)

Update date:2022-08-04

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Authors:

Magnus, Philip

Lewis, Richard T.

Bennett, Frank

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Article abstract of DOI:10.1039/c39890000916

The bridgehead enone (16) was converted into the allylic trisulphide (22)/(23) in a completely stereospecific manner, and the thermal and reduction chemistry of some allylic trisulphides was examined.

Full text of DOI:10.1039/c39890000916

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