Reversible C-H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2] + cation

DOI: 10.1039/c0dt00449a

Source and publish data:

Dalton Transactions p. 7437 - 7439 (2010)

Update date:2022-08-02

Topics:

Authors:

Sewell, Laura J.

Chaplin, Adrian B.

Abdalla, Joseph A. B.

Weller, Andrew S.

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Article abstract of DOI:10.1039/c0dt00449a

[Rh(P^tBuⁱBu₂)₂][BAr ^F₄], formed by removal of H₂ from [RhH ₂(P^tBuⁱBu₂)₂][BAr ^F₄], is in rapid equilibrium between C-H activated Rh(iii) isomers, but reacts as a masked 12-electron [Rh(P^tBu ⁱBu₂)₂]⁺ Rh(i) cation.

Full text of DOI:10.1039/c0dt00449a

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