SYNTHETIC APPLICATIONS OF MASKED O-BENZOQUINONES. A NOVEL TOTAL SYNTHESIS OF (+/-)FORSYTHIDE AGLUCONE DIMETHYL ESTER

DOI: 10.1016/S0040-4039(00)99662-X

Source and publish data:

Tetrahedron Letters p. 2255 - 2256 (1989)

Update date:2022-08-05

Topics:

Authors:

Liao, Chun-Chen

Wei, Ching-Peng

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Article abstract of DOI:10.1016/S0040-4039(00)99662-X

The title compound has been synthesized from methyl vanillate in 10 steps and in a 15percent overall yield; the Diels-Alder reaction of masked o-benzoquinone and the oxa-di-? methane rearrangement are the key reactions.

Full text of DOI:10.1016/S0040-4039(00)99662-X

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