Advantages of Fluoroformates as Carboalkoxylating Reagents for Polar Reactants

DOI: 10.1021/jo00293a033

Source and publish data:

Journal of Organic Chemistry p. 1851 - 1854 (1990)

Update date:2022-07-29

Topics:

Authors:

Dang, Vu Anh

Olofson, R. A.

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Article abstract of DOI:10.1021/jo00293a033

While chloroformates react explosively with DMSO and exothermically with DMF and other tertiary amides, we have found that fluoroformates are stable in these solvents below 100 deg C.Several important classes of hydroxyl and amine-containing organic compo

Full text of DOI:10.1021/jo00293a033

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