Journal of Organic Chemistry p. 1447 - 1459 (1990)
Update date:2022-08-05
Topics: Bicyclic Intramolecular Cycloadditions Alkyne α-amino ketones N-(Acyloxy)iminium Ion
Fisher, Matthew J.
Overman, Larry E.
The intramolecular cyclocondensation of 15 cyclic N-(acyloxy)iminium cations containing tethered alkyne and alkene nucleophiles is reported (eqs 5 and 6).This route to heterotricyclic systems was specifically demonstrated with substrates in which the hete
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