β-SILYL CARBENES

DOI: 10.1016/S0040-4039(01)80433-0

Source and publish data:

Tetrahedron Letters p. 2493 - 2496 (1989)

Update date:2022-09-26

Topics:

Authors:

Creary, Xavier

Wang, You-Xiong

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Article abstract of DOI:10.1016/S0040-4039(01)80433-0

β-Trimethylsilyl carbenes rearrange to form alkenes by facile migration of the β-silyl group.In the norbornyl system, β-hydrogen migration can also compete with silyl migration.

Full text of DOI:10.1016/S0040-4039(01)80433-0

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