Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose

DOI: 10.1016/0022-328X(89)87293-6

Source and publish data:

Journal of Organometallic Chemistry p. 295 - 304 (1989)

Update date:2022-09-26

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Authors:

Sunjic, Vitomir

Habus, Ivan

Snatzke, Guenther

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Article abstract of DOI:10.1016/0022-328X(89)87293-6

(2R,3S)-2-Diphenylphosphinomethyl-3-diphenylphosphinotetrahydropyran (3) has been prepared in 64percent yield from the dimesylate 5, derived from D-galactose.The surprisingly different reactivities of dimesylates 2 and 5 towards diphenylphosphide anion ar

Full text of DOI:10.1016/0022-328X(89)87293-6

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